Hydrogen Energy - Research and Development of New Materials: Electrolytic Hydrogen Production, Hydrogen Fuel Cells, Isotope Effects

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Hydrogen Energy - Research and Development of New Materials: Electrolytic Hydrogen Production, Hydrogen Fuel Cells, Isotope Effects (en)
Водонична енергија - развој нових материјала: електролитичко добијање водоника, водоничне горивне ћелије, изотопски ефекти (sr)
Vodonična energija - razvoj novih materijala: elektrolitičko dobijanje vodonika, vodonične gorivne ćelije, izotopski efekti (sr_RS)
Authors

Publications

Apricot kernel shells pyrolysis controlled by non-isothermal simultaneous thermal analysis (STA)

Manić, Nebojša; Janković, Bojan; Pijović, Milena; Waisi, Hadi; Dodevski, Vladimir; Stojiljković, Dragoslava; Jovanović, Vladimir

(Springer, Dordrecht, 2020)

TY  - JOUR
AU  - Manić, Nebojša
AU  - Janković, Bojan
AU  - Pijović, Milena
AU  - Waisi, Hadi
AU  - Dodevski, Vladimir
AU  - Stojiljković, Dragoslava
AU  - Jovanović, Vladimir
PY  - 2020
UR  - https://machinery.mas.bg.ac.rs/handle/123456789/3420
AB  - In order to clarify relationship between apricot kernel shell biomass slow pyrolysis mechanism and its main constituents (viz. hemicelluloses, cellulose and lignin), the reactivity effects of main constituents on pyrolysis characteristics were determined by the non-isothermal simultaneous thermal analysis. It was found that four-step (parallel) reaction model is suitable for studying the slow pyrolysis process, within the semi-global model which excludes the strong interaction between biomass constituents (pseudo-components). The application of the proposed model was allowed by the results obtained from KAS iterative isoconversional (model-free) approach. The valorization of the model was confirmed by the process optimization. The complex (cumulative) apricot kernel shell pyrolysis rate curves at different heating rates are successfully resolved into the individual decomposition rate curves (arising from thermal conversion of hemicelluloses, cellulose, and primary/secondary lignin fragments) by four-parameter Fraser-Suzuki function. Besides hemicelluloses and cellulose pyrolyses, the proposed model distinguishes primary and secondary lignin reactions, which enhance the gaseous products releasing (primarily CO and CO(2)gases) and charification of the solid residue (increased the bio-char yield).
PB  - Springer, Dordrecht
T2  - Journal of Thermal Analysis and Calorimetry
T1  - Apricot kernel shells pyrolysis controlled by non-isothermal simultaneous thermal analysis (STA)
EP  - 579
IS  - 2
SP  - 565
VL  - 142
DO  - 10.1007/s10973-020-09307-5
ER  - 
@article{
author = "Manić, Nebojša and Janković, Bojan and Pijović, Milena and Waisi, Hadi and Dodevski, Vladimir and Stojiljković, Dragoslava and Jovanović, Vladimir",
year = "2020",
abstract = "In order to clarify relationship between apricot kernel shell biomass slow pyrolysis mechanism and its main constituents (viz. hemicelluloses, cellulose and lignin), the reactivity effects of main constituents on pyrolysis characteristics were determined by the non-isothermal simultaneous thermal analysis. It was found that four-step (parallel) reaction model is suitable for studying the slow pyrolysis process, within the semi-global model which excludes the strong interaction between biomass constituents (pseudo-components). The application of the proposed model was allowed by the results obtained from KAS iterative isoconversional (model-free) approach. The valorization of the model was confirmed by the process optimization. The complex (cumulative) apricot kernel shell pyrolysis rate curves at different heating rates are successfully resolved into the individual decomposition rate curves (arising from thermal conversion of hemicelluloses, cellulose, and primary/secondary lignin fragments) by four-parameter Fraser-Suzuki function. Besides hemicelluloses and cellulose pyrolyses, the proposed model distinguishes primary and secondary lignin reactions, which enhance the gaseous products releasing (primarily CO and CO(2)gases) and charification of the solid residue (increased the bio-char yield).",
publisher = "Springer, Dordrecht",
journal = "Journal of Thermal Analysis and Calorimetry",
title = "Apricot kernel shells pyrolysis controlled by non-isothermal simultaneous thermal analysis (STA)",
pages = "579-565",
number = "2",
volume = "142",
doi = "10.1007/s10973-020-09307-5"
}
Manić, N., Janković, B., Pijović, M., Waisi, H., Dodevski, V., Stojiljković, D.,& Jovanović, V.. (2020). Apricot kernel shells pyrolysis controlled by non-isothermal simultaneous thermal analysis (STA). in Journal of Thermal Analysis and Calorimetry
Springer, Dordrecht., 142(2), 565-579.
https://doi.org/10.1007/s10973-020-09307-5
Manić N, Janković B, Pijović M, Waisi H, Dodevski V, Stojiljković D, Jovanović V. Apricot kernel shells pyrolysis controlled by non-isothermal simultaneous thermal analysis (STA). in Journal of Thermal Analysis and Calorimetry. 2020;142(2):565-579.
doi:10.1007/s10973-020-09307-5 .
Manić, Nebojša, Janković, Bojan, Pijović, Milena, Waisi, Hadi, Dodevski, Vladimir, Stojiljković, Dragoslava, Jovanović, Vladimir, "Apricot kernel shells pyrolysis controlled by non-isothermal simultaneous thermal analysis (STA)" in Journal of Thermal Analysis and Calorimetry, 142, no. 2 (2020):565-579,
https://doi.org/10.1007/s10973-020-09307-5 . .
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Thermo-Analytical Characterization of Various Biomass Feedstocks for Assessments of Light Gaseous Compounds and Solid Residues

Pijović, Milena; Janković, Bojan; Stojiljković, Dragoslava; Radojević, Miloš; Manić, Nebojša

(Springer International Publishing Ag, Cham, 2020)

TY  - CONF
AU  - Pijović, Milena
AU  - Janković, Bojan
AU  - Stojiljković, Dragoslava
AU  - Radojević, Miloš
AU  - Manić, Nebojša
PY  - 2020
UR  - https://machinery.mas.bg.ac.rs/handle/123456789/3300
AB  - Thermo-analytical characterization of selected biomasses (agricultural waste and wood biomass feedstock) through the pyrolysis process was performed under dynamic conditions. Slow pyrolysis (carbonization) regime (with a heating rate below 50 degrees C min(-1)) was selected because it favours the residual solid (bio-carbon/bio-char) in the higher yields (change in the surface area of bio-char with pyrolysis conditions was dependent on the type of biomass feedstock). Comparison of results and discussions related to obtained percentage pyro char yields from thermo-chemical conversion of biomass feedstocks were generated from simultaneous thermal analysis (STA) (TGA-DTG-DTA apparatus). The analysis of gaseous products of pyrolysis was carried out using mass spectrometry (MS) technique. Releasing of the light gaseous compounds (mainly CO, CO2, CH4, and H-2 non-condensable gases) was monitored simultaneously with TGA measurements. Discussion related to this issue was performed from the aspect of the syngas production, as well as the versatility of selected biomasses in the gasification process where the various gasifying agent may be in use.
PB  - Springer International Publishing Ag, Cham
C3  - Computational and Experimental Approaches in Materials Science and Engineering, Cnntech 2019
T1  - Thermo-Analytical Characterization of Various Biomass Feedstocks for Assessments of Light Gaseous Compounds and Solid Residues
EP  - 165
SP  - 139
VL  - 90
DO  - 10.1007/978-3-030-30853-7_9
ER  - 
@conference{
author = "Pijović, Milena and Janković, Bojan and Stojiljković, Dragoslava and Radojević, Miloš and Manić, Nebojša",
year = "2020",
abstract = "Thermo-analytical characterization of selected biomasses (agricultural waste and wood biomass feedstock) through the pyrolysis process was performed under dynamic conditions. Slow pyrolysis (carbonization) regime (with a heating rate below 50 degrees C min(-1)) was selected because it favours the residual solid (bio-carbon/bio-char) in the higher yields (change in the surface area of bio-char with pyrolysis conditions was dependent on the type of biomass feedstock). Comparison of results and discussions related to obtained percentage pyro char yields from thermo-chemical conversion of biomass feedstocks were generated from simultaneous thermal analysis (STA) (TGA-DTG-DTA apparatus). The analysis of gaseous products of pyrolysis was carried out using mass spectrometry (MS) technique. Releasing of the light gaseous compounds (mainly CO, CO2, CH4, and H-2 non-condensable gases) was monitored simultaneously with TGA measurements. Discussion related to this issue was performed from the aspect of the syngas production, as well as the versatility of selected biomasses in the gasification process where the various gasifying agent may be in use.",
publisher = "Springer International Publishing Ag, Cham",
journal = "Computational and Experimental Approaches in Materials Science and Engineering, Cnntech 2019",
title = "Thermo-Analytical Characterization of Various Biomass Feedstocks for Assessments of Light Gaseous Compounds and Solid Residues",
pages = "165-139",
volume = "90",
doi = "10.1007/978-3-030-30853-7_9"
}
Pijović, M., Janković, B., Stojiljković, D., Radojević, M.,& Manić, N.. (2020). Thermo-Analytical Characterization of Various Biomass Feedstocks for Assessments of Light Gaseous Compounds and Solid Residues. in Computational and Experimental Approaches in Materials Science and Engineering, Cnntech 2019
Springer International Publishing Ag, Cham., 90, 139-165.
https://doi.org/10.1007/978-3-030-30853-7_9
Pijović M, Janković B, Stojiljković D, Radojević M, Manić N. Thermo-Analytical Characterization of Various Biomass Feedstocks for Assessments of Light Gaseous Compounds and Solid Residues. in Computational and Experimental Approaches in Materials Science and Engineering, Cnntech 2019. 2020;90:139-165.
doi:10.1007/978-3-030-30853-7_9 .
Pijović, Milena, Janković, Bojan, Stojiljković, Dragoslava, Radojević, Miloš, Manić, Nebojša, "Thermo-Analytical Characterization of Various Biomass Feedstocks for Assessments of Light Gaseous Compounds and Solid Residues" in Computational and Experimental Approaches in Materials Science and Engineering, Cnntech 2019, 90 (2020):139-165,
https://doi.org/10.1007/978-3-030-30853-7_9 . .

Effect of laser shock peening with and without protective coating on the microstructure and mechanical properties of Ti-alloy

Petronić, Sanja; Čolić, Katarina; Đorđević, Branislav R.; Milovanović, D.; Burzić, Meri; Vučetić, Filip

(Elsevier Sci Ltd, Oxford, 2020)

TY  - JOUR
AU  - Petronić, Sanja
AU  - Čolić, Katarina
AU  - Đorđević, Branislav R.
AU  - Milovanović, D.
AU  - Burzić, Meri
AU  - Vučetić, Filip
PY  - 2020
UR  - https://machinery.mas.bg.ac.rs/handle/123456789/3352
AB  - Owing to their good mechanical properties, titanium based alloys are used for machine parts and devices that operate in demanding regimes and environmental conditions. Laser shock peening (LSP) is an innovative technique for improvement of the surface and mechanical characteristics of the material. In this paper, LSP is employed for additional improvement of already good characteristics of Ti- alloy. Laser shock peening is performed on alloy surface, with and without protective and transparent layer and obtained microstructure, surface characteristics and mechanical properties are compared. LSP improved the surface topology and microhardness of material, producing overall better results when the Ti-alloy surface was coated by transparent and protective layer.
PB  - Elsevier Sci Ltd, Oxford
T2  - Optics and Lasers in Engineering
T1  - Effect of laser shock peening with and without protective coating on the microstructure and mechanical properties of Ti-alloy
VL  - 129
DO  - 10.1016/j.optlaseng.2020.106052
ER  - 
@article{
author = "Petronić, Sanja and Čolić, Katarina and Đorđević, Branislav R. and Milovanović, D. and Burzić, Meri and Vučetić, Filip",
year = "2020",
abstract = "Owing to their good mechanical properties, titanium based alloys are used for machine parts and devices that operate in demanding regimes and environmental conditions. Laser shock peening (LSP) is an innovative technique for improvement of the surface and mechanical characteristics of the material. In this paper, LSP is employed for additional improvement of already good characteristics of Ti- alloy. Laser shock peening is performed on alloy surface, with and without protective and transparent layer and obtained microstructure, surface characteristics and mechanical properties are compared. LSP improved the surface topology and microhardness of material, producing overall better results when the Ti-alloy surface was coated by transparent and protective layer.",
publisher = "Elsevier Sci Ltd, Oxford",
journal = "Optics and Lasers in Engineering",
title = "Effect of laser shock peening with and without protective coating on the microstructure and mechanical properties of Ti-alloy",
volume = "129",
doi = "10.1016/j.optlaseng.2020.106052"
}
Petronić, S., Čolić, K., Đorđević, B. R., Milovanović, D., Burzić, M.,& Vučetić, F.. (2020). Effect of laser shock peening with and without protective coating on the microstructure and mechanical properties of Ti-alloy. in Optics and Lasers in Engineering
Elsevier Sci Ltd, Oxford., 129.
https://doi.org/10.1016/j.optlaseng.2020.106052
Petronić S, Čolić K, Đorđević BR, Milovanović D, Burzić M, Vučetić F. Effect of laser shock peening with and without protective coating on the microstructure and mechanical properties of Ti-alloy. in Optics and Lasers in Engineering. 2020;129.
doi:10.1016/j.optlaseng.2020.106052 .
Petronić, Sanja, Čolić, Katarina, Đorđević, Branislav R., Milovanović, D., Burzić, Meri, Vučetić, Filip, "Effect of laser shock peening with and without protective coating on the microstructure and mechanical properties of Ti-alloy" in Optics and Lasers in Engineering, 129 (2020),
https://doi.org/10.1016/j.optlaseng.2020.106052 . .
20
20

Physico-chemical characterization of carbonized apricot kernel shell as precursor for activated carbon preparation in clean technology utilization

Janković, Bojan; Manić, Nebojša; Dodevski, Vladimir; Radović, Ivana; Pijović, Milena; Katnić, Djurica; Tasić, Gvozden

(Elsevier Sci Ltd, Oxford, 2019)

TY  - JOUR
AU  - Janković, Bojan
AU  - Manić, Nebojša
AU  - Dodevski, Vladimir
AU  - Radović, Ivana
AU  - Pijović, Milena
AU  - Katnić, Djurica
AU  - Tasić, Gvozden
PY  - 2019
UR  - https://machinery.mas.bg.ac.rs/handle/123456789/3000
AB  - This paper investigates the ability of waste apricot (Prunus armeniaca) kernel shells (AKS) bio-char prepared by single-step carbonization process at 850 degrees C (residence time of 1 h) for possible removal of toxic elements and organic micro-pollutants. The experiment that was performed as well as parameters used proved to be optimal for bio-char production as adsorbing medium, where last issue is validated by multiform material characterization techniques. It has been shown that the produced bio-char possess highly-porous morphology features, with large specific surface area (328.570 m(2) g(-1)). The obtained product was characterized by various pore sizes (including super-micropores and mesopores with maximum pore size of 2.24 nm) structures. Preliminary results are indicated that obtained bio-char can shows increased affinity to possible adsorption of the small organic molecule contaminants upgraded by its physico-chemical properties. Cost estimation of AKS bio-char production substantiated its cost effectiveness and its good physical and chemical properties for future design in batch adsorption and regeneration tests. It was established that AKS produced bio-char was 2.5 times cheaper than the commercially available activated carbon. Bio-char exhibits promising removal performances for potential adsorption of heavy metal and organic micro-pollutants from wastewaters systems, as indicated by material textures and spectroscopy measurements.
PB  - Elsevier Sci Ltd, Oxford
T2  - Journal of Cleaner Production
T1  - Physico-chemical characterization of carbonized apricot kernel shell as precursor for activated carbon preparation in clean technology utilization
VL  - 236
DO  - 10.1016/j.jclepro.2019.117614
ER  - 
@article{
author = "Janković, Bojan and Manić, Nebojša and Dodevski, Vladimir and Radović, Ivana and Pijović, Milena and Katnić, Djurica and Tasić, Gvozden",
year = "2019",
abstract = "This paper investigates the ability of waste apricot (Prunus armeniaca) kernel shells (AKS) bio-char prepared by single-step carbonization process at 850 degrees C (residence time of 1 h) for possible removal of toxic elements and organic micro-pollutants. The experiment that was performed as well as parameters used proved to be optimal for bio-char production as adsorbing medium, where last issue is validated by multiform material characterization techniques. It has been shown that the produced bio-char possess highly-porous morphology features, with large specific surface area (328.570 m(2) g(-1)). The obtained product was characterized by various pore sizes (including super-micropores and mesopores with maximum pore size of 2.24 nm) structures. Preliminary results are indicated that obtained bio-char can shows increased affinity to possible adsorption of the small organic molecule contaminants upgraded by its physico-chemical properties. Cost estimation of AKS bio-char production substantiated its cost effectiveness and its good physical and chemical properties for future design in batch adsorption and regeneration tests. It was established that AKS produced bio-char was 2.5 times cheaper than the commercially available activated carbon. Bio-char exhibits promising removal performances for potential adsorption of heavy metal and organic micro-pollutants from wastewaters systems, as indicated by material textures and spectroscopy measurements.",
publisher = "Elsevier Sci Ltd, Oxford",
journal = "Journal of Cleaner Production",
title = "Physico-chemical characterization of carbonized apricot kernel shell as precursor for activated carbon preparation in clean technology utilization",
volume = "236",
doi = "10.1016/j.jclepro.2019.117614"
}
Janković, B., Manić, N., Dodevski, V., Radović, I., Pijović, M., Katnić, D.,& Tasić, G.. (2019). Physico-chemical characterization of carbonized apricot kernel shell as precursor for activated carbon preparation in clean technology utilization. in Journal of Cleaner Production
Elsevier Sci Ltd, Oxford., 236.
https://doi.org/10.1016/j.jclepro.2019.117614
Janković B, Manić N, Dodevski V, Radović I, Pijović M, Katnić D, Tasić G. Physico-chemical characterization of carbonized apricot kernel shell as precursor for activated carbon preparation in clean technology utilization. in Journal of Cleaner Production. 2019;236.
doi:10.1016/j.jclepro.2019.117614 .
Janković, Bojan, Manić, Nebojša, Dodevski, Vladimir, Radović, Ivana, Pijović, Milena, Katnić, Djurica, Tasić, Gvozden, "Physico-chemical characterization of carbonized apricot kernel shell as precursor for activated carbon preparation in clean technology utilization" in Journal of Cleaner Production, 236 (2019),
https://doi.org/10.1016/j.jclepro.2019.117614 . .
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