TY  - JOUR
AU  - Krstajić, Nedeljko V.
AU  - Grgur, BN
AU  - Mladenović, Nikola
AU  - Vojnović, MV
AU  - Jaksić, MM
PY  - 1997
UR  - https://machinery.mas.bg.ac.rs/handle/123456789/155
AB  - The kinetics and mechanism of hydrogen evolution at Ti-Ni alloys electrode has been studied by means of steady-state potentiostatic polarization and ac impedance spectrum measurements. Complex-plane spectrum plots are derived for the h.e.r. at one of the most inactive, typical hydridic, Ti-Ni, and one of the most active, typical electrocatalytic, Ti-Ni-3, intermetallic alloy compounds at various potentials. The rate constants of the forward and backward reactions of the corresponding steps were estimated by a nonlinear fitting method. It has been found that the overall reaction proceeds through a coupled Volmer-Heyrovsky mechanism. The electrocatalytic activity decreases in the order TiNi2 > TiNi3 > TiNi4 > Ti2Ni > TiNi > Ti3Ni > TiNi0.7.
PB  - Pergamon-Elsevier Science Ltd, Oxford
T2  - Electrochimica Acta
T1  - The determination of kinetics parameters of the hydrogen evolution on Ti-Ni alloys by ac impedance
EP  - 330
IS  - 2
SP  - 323
VL  - 42
DO  - 10.1016/0013-4686(96)00188-0
ER  - 

@article{
author = "Krstajić, Nedeljko V. and Grgur, BN and Mladenović, Nikola and Vojnović, MV and Jaksić, MM",
year = "1997",
abstract = "The kinetics and mechanism of hydrogen evolution at Ti-Ni alloys electrode has been studied by means of steady-state potentiostatic polarization and ac impedance spectrum measurements. Complex-plane spectrum plots are derived for the h.e.r. at one of the most inactive, typical hydridic, Ti-Ni, and one of the most active, typical electrocatalytic, Ti-Ni-3, intermetallic alloy compounds at various potentials. The rate constants of the forward and backward reactions of the corresponding steps were estimated by a nonlinear fitting method. It has been found that the overall reaction proceeds through a coupled Volmer-Heyrovsky mechanism. The electrocatalytic activity decreases in the order TiNi2 > TiNi3 > TiNi4 > Ti2Ni > TiNi > Ti3Ni > TiNi0.7.",
publisher = "Pergamon-Elsevier Science Ltd, Oxford",
journal = "Electrochimica Acta",
title = "The determination of kinetics parameters of the hydrogen evolution on Ti-Ni alloys by ac impedance",
pages = "330-323",
number = "2",
volume = "42",
doi = "10.1016/0013-4686(96)00188-0"
}

Krstajić, N. V., Grgur, B., Mladenović, N., Vojnović, M.,& Jaksić, M.. (1997). The determination of kinetics parameters of the hydrogen evolution on Ti-Ni alloys by ac impedance. in Electrochimica Acta
Pergamon-Elsevier Science Ltd, Oxford., 42(2), 323-330.
https://doi.org/10.1016/0013-4686(96)00188-0

Krstajić NV, Grgur B, Mladenović N, Vojnović M, Jaksić M. The determination of kinetics parameters of the hydrogen evolution on Ti-Ni alloys by ac impedance. in Electrochimica Acta. 1997;42(2):323-330.
doi:10.1016/0013-4686(96)00188-0 .

Krstajić, Nedeljko V., Grgur, BN, Mladenović, Nikola, Vojnović, MV, Jaksić, MM, "The determination of kinetics parameters of the hydrogen evolution on Ti-Ni alloys by ac impedance" in Electrochimica Acta, 42, no. 2 (1997):323-330,
https://doi.org/10.1016/0013-4686(96)00188-0 . .