Co-Pyrolysis Process of Coal and Waste: Synergistic Effect and Influence of Microscale Conditions
Само за регистроване кориснике
2023
Аутори
Brat, ZagorkaJanković, Bojan
Stojiljković, Dragoslava
Vujanović, Milan
Wang, Xuebin
Manić, Nebojša
Конференцијски прилог (Објављена верзија)
,
SDEWES - International Centre for Sustainable Development of Energy, Water and Environment Systems
Метаподаци
Приказ свих података о документуАпстракт
The pyrolysis process of two low-rank coals (lignite Kostolac and Kolubara), and two waste
materials (spent coffee ground and tyre rubber granulate) as well as their blends, have been
examined by preliminary thermogravimetric analysis. Thermal decomposition experiments were
performed in an N2 atmosphere on raw (pyrolysis) and blend (co-pyrolysis) samples at heating
rates of 10, 15, and 20 K min-1. The lignite-waste blend was created in the following mass
percentage ratios 90:10, 80:20, and 70:30. Based on obtained experimental data, the strong
interactions were identified between the examined lignite and waste materials during copyrolysis,
indicating the presence of a positive synergistic effect. The characteristics of the raw
waste sample and the heating rate were recognized as two key parameters that influenced the
synergy result with lignite sample, in lignite-spent coffee ground blends. For lignite-waste rubber
granulate blends, the blending ratio is critical for benefici...al synergistic effect (ratios of waste
rubber granulate with lignite less than 30% are preferred). The probable synergistic mechanisms
were further explained using performed kinetic analysis by varying the effective activation energy
with temperature and conversion. In addition, the influence of micro-scale condition
characteristics such as heating rate (as the experimental regulatory factor) on the magnitude
response of synergistic effect during co-pyrolysis was also investigated in this work.
Кључне речи:
co-pyrolysis / coal-waste blends / thermogravimetric analysis / synergistic effectИзвор:
Book of Abstracts 18th Confenrece on Sustainable Development of Energy, Water and Environment Systems, 2023, SDEWES2023.0507Издавач:
- SDEWES - International Centre for Sustainable Development of Energy, Water and Environment Systems
- Faculty of Mechanical Engineering and Naval Architecture, Zagreb
Финансирање / пројекти:
Колекције
Институција/група
Mašinski fakultetTY - CONF AU - Brat, Zagorka AU - Janković, Bojan AU - Stojiljković, Dragoslava AU - Vujanović, Milan AU - Wang, Xuebin AU - Manić, Nebojša PY - 2023 UR - https://machinery.mas.bg.ac.rs/handle/123456789/7240 AB - The pyrolysis process of two low-rank coals (lignite Kostolac and Kolubara), and two waste materials (spent coffee ground and tyre rubber granulate) as well as their blends, have been examined by preliminary thermogravimetric analysis. Thermal decomposition experiments were performed in an N2 atmosphere on raw (pyrolysis) and blend (co-pyrolysis) samples at heating rates of 10, 15, and 20 K min-1. The lignite-waste blend was created in the following mass percentage ratios 90:10, 80:20, and 70:30. Based on obtained experimental data, the strong interactions were identified between the examined lignite and waste materials during copyrolysis, indicating the presence of a positive synergistic effect. The characteristics of the raw waste sample and the heating rate were recognized as two key parameters that influenced the synergy result with lignite sample, in lignite-spent coffee ground blends. For lignite-waste rubber granulate blends, the blending ratio is critical for beneficial synergistic effect (ratios of waste rubber granulate with lignite less than 30% are preferred). The probable synergistic mechanisms were further explained using performed kinetic analysis by varying the effective activation energy with temperature and conversion. In addition, the influence of micro-scale condition characteristics such as heating rate (as the experimental regulatory factor) on the magnitude response of synergistic effect during co-pyrolysis was also investigated in this work. PB - SDEWES - International Centre for Sustainable Development of Energy, Water and Environment Systems PB - Faculty of Mechanical Engineering and Naval Architecture, Zagreb C3 - Book of Abstracts 18th Confenrece on Sustainable Development of Energy, Water and Environment Systems T1 - Co-Pyrolysis Process of Coal and Waste: Synergistic Effect and Influence of Microscale Conditions IS - SDEWES2023.0507 UR - https://hdl.handle.net/21.15107/rcub_machinery_7240 ER -
@conference{ author = "Brat, Zagorka and Janković, Bojan and Stojiljković, Dragoslava and Vujanović, Milan and Wang, Xuebin and Manić, Nebojša", year = "2023", abstract = "The pyrolysis process of two low-rank coals (lignite Kostolac and Kolubara), and two waste materials (spent coffee ground and tyre rubber granulate) as well as their blends, have been examined by preliminary thermogravimetric analysis. Thermal decomposition experiments were performed in an N2 atmosphere on raw (pyrolysis) and blend (co-pyrolysis) samples at heating rates of 10, 15, and 20 K min-1. The lignite-waste blend was created in the following mass percentage ratios 90:10, 80:20, and 70:30. Based on obtained experimental data, the strong interactions were identified between the examined lignite and waste materials during copyrolysis, indicating the presence of a positive synergistic effect. The characteristics of the raw waste sample and the heating rate were recognized as two key parameters that influenced the synergy result with lignite sample, in lignite-spent coffee ground blends. For lignite-waste rubber granulate blends, the blending ratio is critical for beneficial synergistic effect (ratios of waste rubber granulate with lignite less than 30% are preferred). The probable synergistic mechanisms were further explained using performed kinetic analysis by varying the effective activation energy with temperature and conversion. In addition, the influence of micro-scale condition characteristics such as heating rate (as the experimental regulatory factor) on the magnitude response of synergistic effect during co-pyrolysis was also investigated in this work.", publisher = "SDEWES - International Centre for Sustainable Development of Energy, Water and Environment Systems, Faculty of Mechanical Engineering and Naval Architecture, Zagreb", journal = "Book of Abstracts 18th Confenrece on Sustainable Development of Energy, Water and Environment Systems", title = "Co-Pyrolysis Process of Coal and Waste: Synergistic Effect and Influence of Microscale Conditions", number = "SDEWES2023.0507", url = "https://hdl.handle.net/21.15107/rcub_machinery_7240" }
Brat, Z., Janković, B., Stojiljković, D., Vujanović, M., Wang, X.,& Manić, N.. (2023). Co-Pyrolysis Process of Coal and Waste: Synergistic Effect and Influence of Microscale Conditions. in Book of Abstracts 18th Confenrece on Sustainable Development of Energy, Water and Environment Systems SDEWES - International Centre for Sustainable Development of Energy, Water and Environment Systems.(SDEWES2023.0507). https://hdl.handle.net/21.15107/rcub_machinery_7240
Brat Z, Janković B, Stojiljković D, Vujanović M, Wang X, Manić N. Co-Pyrolysis Process of Coal and Waste: Synergistic Effect and Influence of Microscale Conditions. in Book of Abstracts 18th Confenrece on Sustainable Development of Energy, Water and Environment Systems. 2023;(SDEWES2023.0507). https://hdl.handle.net/21.15107/rcub_machinery_7240 .
Brat, Zagorka, Janković, Bojan, Stojiljković, Dragoslava, Vujanović, Milan, Wang, Xuebin, Manić, Nebojša, "Co-Pyrolysis Process of Coal and Waste: Synergistic Effect and Influence of Microscale Conditions" in Book of Abstracts 18th Confenrece on Sustainable Development of Energy, Water and Environment Systems, no. SDEWES2023.0507 (2023), https://hdl.handle.net/21.15107/rcub_machinery_7240 .