Structural and electrical properties of ferroelectric poly(vinylidene fluoride) and mechanically activated ZnO nanoparticle composite films
Authors
Peleš, AdrianaAleksić, Obrad
Pavlović, Vera P.
Djoković, Vladimir
Dojčilović, Radovan
Nikolić, Z.
Marinković, Filip
Mitrić, Miodrag
Blagojević, Vladimir A.
Vlahović, Branislav
Pavlović, Vladimir B.
Article (Accepted Version)
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The influence of the mechanical activation of ZnO nanoparticle fillers on the structural and electrical properties of the matrix of poly(vinylidenefluoride)-ZnO (PVDF-ZnO) films was investigated. Transmission electron microscopy and scanning electron microscopy analyses showed that mechanical activation in a high energy planetary ball mill reduces the size of ZnO particles. X-ray diffraction and Raman spectroscopy revealed that PVDF crystallized predominantly as the gamma-phase. Non-activated ZnO filler reduces the degree of the crystallinity of the matrix and promotes crystallization of alpha-phase of PVDF in the film, while the fillers activated for 5 and 10 min induce crystallization of beta-phase, indicating that mechanical activation of the filler can be used as a general method for fabrication of PVDF composites with increased content of piezoelectric beta-phase crystals. Dielectric spectroscopy measurements show that polymer composite with the high content of beta-phase (with Zn...O filler activated for 5 min) exhibits the highest value of dielectric permittivity in 150-400 K range of temperatures. Kinetic analysis shows combined effects of increased surface area and increased concentration of surface defects on the interactions between polymer chains and activated nanoparticles.
Keywords:
ZnO / PVDF / polymer composites / mechanical activation / dielectric properties / crystallizationSource:
Physica Scripta, 2018, 93, 10, 105801-Publisher:
- IOP Publishing
Funding / projects:
- Size-, shape- and structure- dependent properties of nanoparticles and nanocomposites (RS-MESTD-Basic Research (BR or ON)-172056)
- Directed synthesis, structure and properties of multifunctional materials (RS-MESTD-Basic Research (BR or ON)-172057)
- Materials of Reduced Dimensions for Efficient Light Harvesting and Energy conversion (RS-MESTD-Integrated and Interdisciplinary Research (IIR or III)-45020)
- NSF CREST [HRD-0833184]
- NASA [NNX09AV07A]
Note:
- This is the peer-reviewed version of the article: Peleš, A., Aleksić, O., Pavlović, V.P., Djoković, V., Dojčilović, R., Nikolić, Z., Marinković, F., Mitrić, M., Blagojević, V., Vlahović, B., Pavlović, V.B., 2018. Structural and electrical properties of ferroelectric poly(vinylidene fluoride) and mechanically activated ZnO nanoparticle composite films. Physica Scripta 93(10), 105801. https://doi.org/10.1088/1402-4896/aad749
Related info:
- Version of
https://doi.org/10.1088/1402-4896/aad749 - Version of
https://machinery.mas.bg.ac.rs/handle/123456789/2871
DOI: 10.1088/1402-4896/aad749
ISSN: 0031-8949 (Print); 1402-4896 (Online)
WoS: 000442645300001
Scopus: 2-s2.0-85054040483
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Mašinski fakultetTY - JOUR AU - Peleš, Adriana AU - Aleksić, Obrad AU - Pavlović, Vera P. AU - Djoković, Vladimir AU - Dojčilović, Radovan AU - Nikolić, Z. AU - Marinković, Filip AU - Mitrić, Miodrag AU - Blagojević, Vladimir A. AU - Vlahović, Branislav AU - Pavlović, Vladimir B. PY - 2018 UR - https://machinery.mas.bg.ac.rs/handle/123456789/4057 AB - The influence of the mechanical activation of ZnO nanoparticle fillers on the structural and electrical properties of the matrix of poly(vinylidenefluoride)-ZnO (PVDF-ZnO) films was investigated. Transmission electron microscopy and scanning electron microscopy analyses showed that mechanical activation in a high energy planetary ball mill reduces the size of ZnO particles. X-ray diffraction and Raman spectroscopy revealed that PVDF crystallized predominantly as the gamma-phase. Non-activated ZnO filler reduces the degree of the crystallinity of the matrix and promotes crystallization of alpha-phase of PVDF in the film, while the fillers activated for 5 and 10 min induce crystallization of beta-phase, indicating that mechanical activation of the filler can be used as a general method for fabrication of PVDF composites with increased content of piezoelectric beta-phase crystals. Dielectric spectroscopy measurements show that polymer composite with the high content of beta-phase (with ZnO filler activated for 5 min) exhibits the highest value of dielectric permittivity in 150-400 K range of temperatures. Kinetic analysis shows combined effects of increased surface area and increased concentration of surface defects on the interactions between polymer chains and activated nanoparticles. PB - IOP Publishing T2 - Physica Scripta T1 - Structural and electrical properties of ferroelectric poly(vinylidene fluoride) and mechanically activated ZnO nanoparticle composite films IS - 10 SP - 105801 VL - 93 DO - 10.1088/1402-4896/aad749 ER -
@article{ author = "Peleš, Adriana and Aleksić, Obrad and Pavlović, Vera P. and Djoković, Vladimir and Dojčilović, Radovan and Nikolić, Z. and Marinković, Filip and Mitrić, Miodrag and Blagojević, Vladimir A. and Vlahović, Branislav and Pavlović, Vladimir B.", year = "2018", abstract = "The influence of the mechanical activation of ZnO nanoparticle fillers on the structural and electrical properties of the matrix of poly(vinylidenefluoride)-ZnO (PVDF-ZnO) films was investigated. Transmission electron microscopy and scanning electron microscopy analyses showed that mechanical activation in a high energy planetary ball mill reduces the size of ZnO particles. X-ray diffraction and Raman spectroscopy revealed that PVDF crystallized predominantly as the gamma-phase. Non-activated ZnO filler reduces the degree of the crystallinity of the matrix and promotes crystallization of alpha-phase of PVDF in the film, while the fillers activated for 5 and 10 min induce crystallization of beta-phase, indicating that mechanical activation of the filler can be used as a general method for fabrication of PVDF composites with increased content of piezoelectric beta-phase crystals. Dielectric spectroscopy measurements show that polymer composite with the high content of beta-phase (with ZnO filler activated for 5 min) exhibits the highest value of dielectric permittivity in 150-400 K range of temperatures. Kinetic analysis shows combined effects of increased surface area and increased concentration of surface defects on the interactions between polymer chains and activated nanoparticles.", publisher = "IOP Publishing", journal = "Physica Scripta", title = "Structural and electrical properties of ferroelectric poly(vinylidene fluoride) and mechanically activated ZnO nanoparticle composite films", number = "10", pages = "105801", volume = "93", doi = "10.1088/1402-4896/aad749" }
Peleš, A., Aleksić, O., Pavlović, V. P., Djoković, V., Dojčilović, R., Nikolić, Z., Marinković, F., Mitrić, M., Blagojević, V. A., Vlahović, B.,& Pavlović, V. B.. (2018). Structural and electrical properties of ferroelectric poly(vinylidene fluoride) and mechanically activated ZnO nanoparticle composite films. in Physica Scripta IOP Publishing., 93(10), 105801. https://doi.org/10.1088/1402-4896/aad749
Peleš A, Aleksić O, Pavlović VP, Djoković V, Dojčilović R, Nikolić Z, Marinković F, Mitrić M, Blagojević VA, Vlahović B, Pavlović VB. Structural and electrical properties of ferroelectric poly(vinylidene fluoride) and mechanically activated ZnO nanoparticle composite films. in Physica Scripta. 2018;93(10):105801. doi:10.1088/1402-4896/aad749 .
Peleš, Adriana, Aleksić, Obrad, Pavlović, Vera P., Djoković, Vladimir, Dojčilović, Radovan, Nikolić, Z., Marinković, Filip, Mitrić, Miodrag, Blagojević, Vladimir A., Vlahović, Branislav, Pavlović, Vladimir B., "Structural and electrical properties of ferroelectric poly(vinylidene fluoride) and mechanically activated ZnO nanoparticle composite films" in Physica Scripta, 93, no. 10 (2018):105801, https://doi.org/10.1088/1402-4896/aad749 . .