dc.creator | Pijović, Milena | |
dc.creator | Manić, Nebojša | |
dc.creator | Vasić-Anicijević, Dragana | |
dc.creator | Krstić, Aleksandar | |
dc.creator | Mitrić, Miodrag | |
dc.creator | Matić, Tamara | |
dc.creator | Janković, Bojan | |
dc.date.accessioned | 2022-09-19T19:31:26Z | |
dc.date.available | 2022-09-19T19:31:26Z | |
dc.date.issued | 2022 | |
dc.identifier.issn | 0925-9635 | |
dc.identifier.uri | https://machinery.mas.bg.ac.rs/handle/123456789/3760 | |
dc.description.abstract | Pyrolytic tire (PT) chars were first produced from waste car tires (WCT) through carbonization process at 800 degrees C, for different retention times. Then, best PT-char sample by its physicochemical properties (WCT 800(1 h)) was further tested for its ability to adsorb Rhodamine B (RhB) dye from aqueous solutions. Structural characterization of synthesized material showed existence of graphene-based material, with average pore diameter of 22.8 nm and specific surface area of 55.8 m2.g- 1. Obtained carbon material meets specifications of commercial carbon black (CB). The yield of 33.6% of CB recovered has been achieved. Under the optimal conditions, 99.57% of RhB was removed. Adsorption of RhB obeys pseudo second-order model and Langmuir isotherm model. DFT (the density functional theory) was revealed that effective bonding of RhB onto WCT 800 originates from pi-electron interactions with aromatic moieties and chemical (or at least the electrostatic) interactions, between positive nitrogen and electron-rich surface groups. | en |
dc.publisher | Elsevier Science Sa, Lausanne | |
dc.relation | info:eu-repo/grantAgreement/MESTD/inst-2020/200105/RS// | |
dc.relation | info:eu-repo/grantAgreement/MESTD/inst-2020/200017/RS// | |
dc.rights | restrictedAccess | |
dc.source | Diamond and Related Materials | |
dc.subject | Waste tires | en |
dc.subject | Surface properties | en |
dc.subject | Recycling | en |
dc.subject | Pyrolysis | en |
dc.subject | Graphene-based adsorbent | en |
dc.subject | DFT | en |
dc.title | Simple and effective one-step production of high-quality mesoporous pyrolytic char from waste tires: Rhodamine B adsorption kinetics and density functional theory (DFT) study | en |
dc.type | article | |
dc.rights.license | ARR | |
dc.citation.other | 121: - | |
dc.citation.rank | M22 | |
dc.citation.volume | 121 | |
dc.identifier.doi | 10.1016/j.diamond.2021.108768 | |
dc.identifier.scopus | 2-s2.0-85121014167 | |
dc.identifier.wos | 000733634900004 | |
dc.type.version | publishedVersion | |