Morphology of char particles from coal pyrolysis in a pressurized entrained flow reactor: Effects of pressure and atmosphere
Само за регистроване кориснике
2022
Аутори
Zhang, JiayeChen, Chongming
Zhou, Ao
Rahman, Zia Ur
Wang, Xuebin
Stojiljković, Dragoslava
Manić, Nebojša
Vujanović, Milan
Tan, Houzhang
Чланак у часопису (Објављена верзија)
Метаподаци
Приказ свих података о документуАпстракт
A pressurized drop tube furnace was used to study the pyrolysis behavior of bituminous and lignite coal at elevated pressure. Experiments were conducted at the pressure range from 1 to 10 atm in 100% N-2 or 100% CO2 atmosphere. The volatile yields, char morphology, swelling ratio, and pore structure were discussed in detail. The results show that the pressure, atmosphere and coal rank could effect on the volatile releasing and char evolution significantly. In N-2 atmosphere, the total volatile yields of YL and NM coal decrease as the pressure elevated, while in CO2 atmosphere, the mass release of NM coal increases at high pressure contributed by the reaction of CO2 with organic macromolecule inside the particles; different with bituminous coal, no significant swelling behavior is found with the increase of pressure; the BET surface area of YL char decreases as the pressure increases, while for lignite coal, in N-2 atmosphere and at high pressure, less macro pores are formed, which coul...d contribute to the BET surface area. While in CO2 atmosphere, the CO2-macromocular organic reaction would promote the volatile releasing, and the BET surface area decreases significantly at high pressure.
Кључне речи:
Swelling behavior / Pressurized pyrolysis / Pressurized drop tube furnace / Char morphologyИзвор:
Energy, 2022, 238Издавач:
- Pergamon-Elsevier Science Ltd, Oxford
Финансирање / пројекти:
- National Natural Science Foundation of China [51761125012, 51676157]
- Natural Science Basic Research Plan in Shaanxi Province of China [2021JC-03]
DOI: 10.1016/j.energy.2021.121846
ISSN: 0360-5442
WoS: 000701940800006
Scopus: 2-s2.0-85113469521
Колекције
Институција/група
Mašinski fakultetTY - JOUR AU - Zhang, Jiaye AU - Chen, Chongming AU - Zhou, Ao AU - Rahman, Zia Ur AU - Wang, Xuebin AU - Stojiljković, Dragoslava AU - Manić, Nebojša AU - Vujanović, Milan AU - Tan, Houzhang PY - 2022 UR - https://machinery.mas.bg.ac.rs/handle/123456789/3752 AB - A pressurized drop tube furnace was used to study the pyrolysis behavior of bituminous and lignite coal at elevated pressure. Experiments were conducted at the pressure range from 1 to 10 atm in 100% N-2 or 100% CO2 atmosphere. The volatile yields, char morphology, swelling ratio, and pore structure were discussed in detail. The results show that the pressure, atmosphere and coal rank could effect on the volatile releasing and char evolution significantly. In N-2 atmosphere, the total volatile yields of YL and NM coal decrease as the pressure elevated, while in CO2 atmosphere, the mass release of NM coal increases at high pressure contributed by the reaction of CO2 with organic macromolecule inside the particles; different with bituminous coal, no significant swelling behavior is found with the increase of pressure; the BET surface area of YL char decreases as the pressure increases, while for lignite coal, in N-2 atmosphere and at high pressure, less macro pores are formed, which could contribute to the BET surface area. While in CO2 atmosphere, the CO2-macromocular organic reaction would promote the volatile releasing, and the BET surface area decreases significantly at high pressure. PB - Pergamon-Elsevier Science Ltd, Oxford T2 - Energy T1 - Morphology of char particles from coal pyrolysis in a pressurized entrained flow reactor: Effects of pressure and atmosphere VL - 238 DO - 10.1016/j.energy.2021.121846 ER -
@article{ author = "Zhang, Jiaye and Chen, Chongming and Zhou, Ao and Rahman, Zia Ur and Wang, Xuebin and Stojiljković, Dragoslava and Manić, Nebojša and Vujanović, Milan and Tan, Houzhang", year = "2022", abstract = "A pressurized drop tube furnace was used to study the pyrolysis behavior of bituminous and lignite coal at elevated pressure. Experiments were conducted at the pressure range from 1 to 10 atm in 100% N-2 or 100% CO2 atmosphere. The volatile yields, char morphology, swelling ratio, and pore structure were discussed in detail. The results show that the pressure, atmosphere and coal rank could effect on the volatile releasing and char evolution significantly. In N-2 atmosphere, the total volatile yields of YL and NM coal decrease as the pressure elevated, while in CO2 atmosphere, the mass release of NM coal increases at high pressure contributed by the reaction of CO2 with organic macromolecule inside the particles; different with bituminous coal, no significant swelling behavior is found with the increase of pressure; the BET surface area of YL char decreases as the pressure increases, while for lignite coal, in N-2 atmosphere and at high pressure, less macro pores are formed, which could contribute to the BET surface area. While in CO2 atmosphere, the CO2-macromocular organic reaction would promote the volatile releasing, and the BET surface area decreases significantly at high pressure.", publisher = "Pergamon-Elsevier Science Ltd, Oxford", journal = "Energy", title = "Morphology of char particles from coal pyrolysis in a pressurized entrained flow reactor: Effects of pressure and atmosphere", volume = "238", doi = "10.1016/j.energy.2021.121846" }
Zhang, J., Chen, C., Zhou, A., Rahman, Z. U., Wang, X., Stojiljković, D., Manić, N., Vujanović, M.,& Tan, H.. (2022). Morphology of char particles from coal pyrolysis in a pressurized entrained flow reactor: Effects of pressure and atmosphere. in Energy Pergamon-Elsevier Science Ltd, Oxford., 238. https://doi.org/10.1016/j.energy.2021.121846
Zhang J, Chen C, Zhou A, Rahman ZU, Wang X, Stojiljković D, Manić N, Vujanović M, Tan H. Morphology of char particles from coal pyrolysis in a pressurized entrained flow reactor: Effects of pressure and atmosphere. in Energy. 2022;238. doi:10.1016/j.energy.2021.121846 .
Zhang, Jiaye, Chen, Chongming, Zhou, Ao, Rahman, Zia Ur, Wang, Xuebin, Stojiljković, Dragoslava, Manić, Nebojša, Vujanović, Milan, Tan, Houzhang, "Morphology of char particles from coal pyrolysis in a pressurized entrained flow reactor: Effects of pressure and atmosphere" in Energy, 238 (2022), https://doi.org/10.1016/j.energy.2021.121846 . .