Experimental Study of the Phase Equilibria in the Ternary Ga-Ge-Zn System
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2022
Authors
Đorđević, AleksandarPremović-Zecević, Milena
Minić, Dusko
Manasijević, Dragan
Radicević, Branko
Kolarević, Nenad
Ristić, Vladica
Article (Published version)
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In the current study the ternary Ga-Ge-Zn system was experimentally and analytically tested. The ternary system is chosen due to the importance of germanium-based alloys in the electronic industry and their special application as memory materials. There are no previous studies related to the Ga-Ge-Zn system up to this paper. Used experimental techniques were differential thermal analysis, scanning electron microscopy with energy dispersive spectrometry, x-ray powder diffraction, electrical conductivity and hardness tests. The experimentally obtained results were compared with the results of thermodynamic calculation of phase equilibria using the calculation of phase diagram (CALPHAD) method and literature data. Calculated phase diagrams were three vertical sections (Ga-GeZn, Ge-GaZn and Zn-GaGe), three isothermal sections (100, 200 and 300 degrees C) and liquidus projection with invariant reactions. Good agreements between calculated phase diagrams and experimental data have been obtai...ned without introducing ternary thermodynamic parameters.
Keywords:
phase diagrams / liquidus projection / Ga-Ge-Zn system / experimental testsSource:
Journal of Phase Equilibria and Diffusion, 2022, 43, 2, 176-192Publisher:
- Springer, New York
Funding / projects:
- National Nature Science Foundation of China [51950410600]
- Advanced multicomponent metal systems and nanostructured materials with diverse functional properties (RS-MESTD-Basic Research (BR or ON)-172037)
DOI: 10.1007/s11669-022-00952-x
ISSN: 1547-7037
WoS: 000782737300001
Scopus: 2-s2.0-85128071829
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Mašinski fakultetTY - JOUR AU - Đorđević, Aleksandar AU - Premović-Zecević, Milena AU - Minić, Dusko AU - Manasijević, Dragan AU - Radicević, Branko AU - Kolarević, Nenad AU - Ristić, Vladica PY - 2022 UR - https://machinery.mas.bg.ac.rs/handle/123456789/3701 AB - In the current study the ternary Ga-Ge-Zn system was experimentally and analytically tested. The ternary system is chosen due to the importance of germanium-based alloys in the electronic industry and their special application as memory materials. There are no previous studies related to the Ga-Ge-Zn system up to this paper. Used experimental techniques were differential thermal analysis, scanning electron microscopy with energy dispersive spectrometry, x-ray powder diffraction, electrical conductivity and hardness tests. The experimentally obtained results were compared with the results of thermodynamic calculation of phase equilibria using the calculation of phase diagram (CALPHAD) method and literature data. Calculated phase diagrams were three vertical sections (Ga-GeZn, Ge-GaZn and Zn-GaGe), three isothermal sections (100, 200 and 300 degrees C) and liquidus projection with invariant reactions. Good agreements between calculated phase diagrams and experimental data have been obtained without introducing ternary thermodynamic parameters. PB - Springer, New York T2 - Journal of Phase Equilibria and Diffusion T1 - Experimental Study of the Phase Equilibria in the Ternary Ga-Ge-Zn System EP - 192 IS - 2 SP - 176 VL - 43 DO - 10.1007/s11669-022-00952-x ER -
@article{ author = "Đorđević, Aleksandar and Premović-Zecević, Milena and Minić, Dusko and Manasijević, Dragan and Radicević, Branko and Kolarević, Nenad and Ristić, Vladica", year = "2022", abstract = "In the current study the ternary Ga-Ge-Zn system was experimentally and analytically tested. The ternary system is chosen due to the importance of germanium-based alloys in the electronic industry and their special application as memory materials. There are no previous studies related to the Ga-Ge-Zn system up to this paper. Used experimental techniques were differential thermal analysis, scanning electron microscopy with energy dispersive spectrometry, x-ray powder diffraction, electrical conductivity and hardness tests. The experimentally obtained results were compared with the results of thermodynamic calculation of phase equilibria using the calculation of phase diagram (CALPHAD) method and literature data. Calculated phase diagrams were three vertical sections (Ga-GeZn, Ge-GaZn and Zn-GaGe), three isothermal sections (100, 200 and 300 degrees C) and liquidus projection with invariant reactions. Good agreements between calculated phase diagrams and experimental data have been obtained without introducing ternary thermodynamic parameters.", publisher = "Springer, New York", journal = "Journal of Phase Equilibria and Diffusion", title = "Experimental Study of the Phase Equilibria in the Ternary Ga-Ge-Zn System", pages = "192-176", number = "2", volume = "43", doi = "10.1007/s11669-022-00952-x" }
Đorđević, A., Premović-Zecević, M., Minić, D., Manasijević, D., Radicević, B., Kolarević, N.,& Ristić, V.. (2022). Experimental Study of the Phase Equilibria in the Ternary Ga-Ge-Zn System. in Journal of Phase Equilibria and Diffusion Springer, New York., 43(2), 176-192. https://doi.org/10.1007/s11669-022-00952-x
Đorđević A, Premović-Zecević M, Minić D, Manasijević D, Radicević B, Kolarević N, Ristić V. Experimental Study of the Phase Equilibria in the Ternary Ga-Ge-Zn System. in Journal of Phase Equilibria and Diffusion. 2022;43(2):176-192. doi:10.1007/s11669-022-00952-x .
Đorđević, Aleksandar, Premović-Zecević, Milena, Minić, Dusko, Manasijević, Dragan, Radicević, Branko, Kolarević, Nenad, Ristić, Vladica, "Experimental Study of the Phase Equilibria in the Ternary Ga-Ge-Zn System" in Journal of Phase Equilibria and Diffusion, 43, no. 2 (2022):176-192, https://doi.org/10.1007/s11669-022-00952-x . .