Thermogravimetric and kinetic analysis of biomass and polyurethane foam mixtures Co-Pyrolysis
Само за регистроване кориснике
2021
Аутори
Stancin, H.Mikulcić, H.
Manić, Nebojša
Stojiljković, Dragoslava
Vujanović, M.
Wang, Xuebin
Duić, N.
Чланак у часопису (Објављена верзија)
Метаподаци
Приказ свих података о документуАпстракт
Alternative fuels are crucial for the decarbonisation of high-energy demanding processes. The utilisation of waste materials to produce alternative fuels is especially interesting since, the co-pyrolysis of waste plastics and biomass was lately introduced as promising method since the synergistic effect might enhance the product properties compared to those from individual pyrolysis. Furthermore, the utilisation of waste biomass, like sawdust, is interesting since it does not influence the sustainability of biomass consumption, and even more, it avoids the usage of raw feedstock. Thermogravimetric analysis is per -formed to determine the thermal degradation behaviour and kinetic parameters of investigated mixtures to find the most appropriate utilisation method. Co-pyrolysis was conducted for three mixtures with the following biomass/polyurethane ratios: 75-25%, 50-50%, 25-75%, over a temperature range of 30-800 degrees C, at three heating rates 5,10 and 20 degrees C/min, under an iner...t atmosphere. Obtained results were subjected to comprehensive kinetic analysis to determine effective activation energy using the iso-conversional model-free methods and provide a detailed analysis of the samples' thermal degradation process. This work aimed to identify the main thermal decomposition stages during co-pyrolysis of biomass and polyurethane mixtures and provide the mixture composition's influence on the considered thermochemical conversion process.
Кључне речи:
Thermogravimetric analysis / Sawdust / Polyurethane / Kinetic analysis / Co-pyrolysisИзвор:
Energy, 2021, 237Издавач:
- Pergamon-Elsevier Science Ltd, Oxford
DOI: 10.1016/j.energy.2021.121592
ISSN: 0360-5442
WoS: 000709144800004
Scopus: 2-s2.0-85111512771
Колекције
Институција/група
Mašinski fakultetTY - JOUR AU - Stancin, H. AU - Mikulcić, H. AU - Manić, Nebojša AU - Stojiljković, Dragoslava AU - Vujanović, M. AU - Wang, Xuebin AU - Duić, N. PY - 2021 UR - https://machinery.mas.bg.ac.rs/handle/123456789/3494 AB - Alternative fuels are crucial for the decarbonisation of high-energy demanding processes. The utilisation of waste materials to produce alternative fuels is especially interesting since, the co-pyrolysis of waste plastics and biomass was lately introduced as promising method since the synergistic effect might enhance the product properties compared to those from individual pyrolysis. Furthermore, the utilisation of waste biomass, like sawdust, is interesting since it does not influence the sustainability of biomass consumption, and even more, it avoids the usage of raw feedstock. Thermogravimetric analysis is per -formed to determine the thermal degradation behaviour and kinetic parameters of investigated mixtures to find the most appropriate utilisation method. Co-pyrolysis was conducted for three mixtures with the following biomass/polyurethane ratios: 75-25%, 50-50%, 25-75%, over a temperature range of 30-800 degrees C, at three heating rates 5,10 and 20 degrees C/min, under an inert atmosphere. Obtained results were subjected to comprehensive kinetic analysis to determine effective activation energy using the iso-conversional model-free methods and provide a detailed analysis of the samples' thermal degradation process. This work aimed to identify the main thermal decomposition stages during co-pyrolysis of biomass and polyurethane mixtures and provide the mixture composition's influence on the considered thermochemical conversion process. PB - Pergamon-Elsevier Science Ltd, Oxford T2 - Energy T1 - Thermogravimetric and kinetic analysis of biomass and polyurethane foam mixtures Co-Pyrolysis VL - 237 DO - 10.1016/j.energy.2021.121592 ER -
@article{ author = "Stancin, H. and Mikulcić, H. and Manić, Nebojša and Stojiljković, Dragoslava and Vujanović, M. and Wang, Xuebin and Duić, N.", year = "2021", abstract = "Alternative fuels are crucial for the decarbonisation of high-energy demanding processes. The utilisation of waste materials to produce alternative fuels is especially interesting since, the co-pyrolysis of waste plastics and biomass was lately introduced as promising method since the synergistic effect might enhance the product properties compared to those from individual pyrolysis. Furthermore, the utilisation of waste biomass, like sawdust, is interesting since it does not influence the sustainability of biomass consumption, and even more, it avoids the usage of raw feedstock. Thermogravimetric analysis is per -formed to determine the thermal degradation behaviour and kinetic parameters of investigated mixtures to find the most appropriate utilisation method. Co-pyrolysis was conducted for three mixtures with the following biomass/polyurethane ratios: 75-25%, 50-50%, 25-75%, over a temperature range of 30-800 degrees C, at three heating rates 5,10 and 20 degrees C/min, under an inert atmosphere. Obtained results were subjected to comprehensive kinetic analysis to determine effective activation energy using the iso-conversional model-free methods and provide a detailed analysis of the samples' thermal degradation process. This work aimed to identify the main thermal decomposition stages during co-pyrolysis of biomass and polyurethane mixtures and provide the mixture composition's influence on the considered thermochemical conversion process.", publisher = "Pergamon-Elsevier Science Ltd, Oxford", journal = "Energy", title = "Thermogravimetric and kinetic analysis of biomass and polyurethane foam mixtures Co-Pyrolysis", volume = "237", doi = "10.1016/j.energy.2021.121592" }
Stancin, H., Mikulcić, H., Manić, N., Stojiljković, D., Vujanović, M., Wang, X.,& Duić, N.. (2021). Thermogravimetric and kinetic analysis of biomass and polyurethane foam mixtures Co-Pyrolysis. in Energy Pergamon-Elsevier Science Ltd, Oxford., 237. https://doi.org/10.1016/j.energy.2021.121592
Stancin H, Mikulcić H, Manić N, Stojiljković D, Vujanović M, Wang X, Duić N. Thermogravimetric and kinetic analysis of biomass and polyurethane foam mixtures Co-Pyrolysis. in Energy. 2021;237. doi:10.1016/j.energy.2021.121592 .
Stancin, H., Mikulcić, H., Manić, Nebojša, Stojiljković, Dragoslava, Vujanović, M., Wang, Xuebin, Duić, N., "Thermogravimetric and kinetic analysis of biomass and polyurethane foam mixtures Co-Pyrolysis" in Energy, 237 (2021), https://doi.org/10.1016/j.energy.2021.121592 . .