Endohedral fullerenes: Biomedical approach
Abstract
Background: Fullerenes can form three distinct types of binding sites: surface, substitutional and endohedral. Numerous metallofullerenes have been synthesized by the inclusion of metal sources in the graphite used for fullerene generation, and several noble gasses and small atoms have also been implanted with ion beam collision experiments. Methods: Theoretical calculations has been done by HyperChem 4.5 software computational program using ZINDO/1 method. For experimental research Bucky System 2 fullerenes production system (MER Corporation, Tucson, Arizona) has been used. Results: According to our calculation, value of HOMO-LUMO gep, for Ca"C60, is 0.11816 eV, and for Cu"C60 is 5.255 eV. Total charge density of endohedral complex Cu"C60 is under 3/2 mode arranged. Conclusion: According to this consideration, copper which is incorporated in C60 will have more important rule in living organism than endohedral Ca"C60 complex. Because of their structural, electronic and chemical propert...ies endohedral complexes X"C60 can be applied in different fields of material science, chemistry, biomedicine and engineering.
Keywords:
Water clusters / Molecule C60 / Endohedral complex / Copper / Clathrin / Charge density / CalciumSource:
Archive of Oncology, 1997, 5, 3, 151-154Collections
Institution/Community
Mašinski fakultetTY - JOUR AU - Matija, Lidija PY - 1997 UR - https://machinery.mas.bg.ac.rs/handle/123456789/142 AB - Background: Fullerenes can form three distinct types of binding sites: surface, substitutional and endohedral. Numerous metallofullerenes have been synthesized by the inclusion of metal sources in the graphite used for fullerene generation, and several noble gasses and small atoms have also been implanted with ion beam collision experiments. Methods: Theoretical calculations has been done by HyperChem 4.5 software computational program using ZINDO/1 method. For experimental research Bucky System 2 fullerenes production system (MER Corporation, Tucson, Arizona) has been used. Results: According to our calculation, value of HOMO-LUMO gep, for Ca"C60, is 0.11816 eV, and for Cu"C60 is 5.255 eV. Total charge density of endohedral complex Cu"C60 is under 3/2 mode arranged. Conclusion: According to this consideration, copper which is incorporated in C60 will have more important rule in living organism than endohedral Ca"C60 complex. Because of their structural, electronic and chemical properties endohedral complexes X"C60 can be applied in different fields of material science, chemistry, biomedicine and engineering. T2 - Archive of Oncology T1 - Endohedral fullerenes: Biomedical approach EP - 154 IS - 3 SP - 151 VL - 5 UR - https://hdl.handle.net/21.15107/rcub_machinery_142 ER -
@article{ author = "Matija, Lidija", year = "1997", abstract = "Background: Fullerenes can form three distinct types of binding sites: surface, substitutional and endohedral. Numerous metallofullerenes have been synthesized by the inclusion of metal sources in the graphite used for fullerene generation, and several noble gasses and small atoms have also been implanted with ion beam collision experiments. Methods: Theoretical calculations has been done by HyperChem 4.5 software computational program using ZINDO/1 method. For experimental research Bucky System 2 fullerenes production system (MER Corporation, Tucson, Arizona) has been used. Results: According to our calculation, value of HOMO-LUMO gep, for Ca"C60, is 0.11816 eV, and for Cu"C60 is 5.255 eV. Total charge density of endohedral complex Cu"C60 is under 3/2 mode arranged. Conclusion: According to this consideration, copper which is incorporated in C60 will have more important rule in living organism than endohedral Ca"C60 complex. Because of their structural, electronic and chemical properties endohedral complexes X"C60 can be applied in different fields of material science, chemistry, biomedicine and engineering.", journal = "Archive of Oncology", title = "Endohedral fullerenes: Biomedical approach", pages = "154-151", number = "3", volume = "5", url = "https://hdl.handle.net/21.15107/rcub_machinery_142" }
Matija, L.. (1997). Endohedral fullerenes: Biomedical approach. in Archive of Oncology, 5(3), 151-154. https://hdl.handle.net/21.15107/rcub_machinery_142
Matija L. Endohedral fullerenes: Biomedical approach. in Archive of Oncology. 1997;5(3):151-154. https://hdl.handle.net/21.15107/rcub_machinery_142 .
Matija, Lidija, "Endohedral fullerenes: Biomedical approach" in Archive of Oncology, 5, no. 3 (1997):151-154, https://hdl.handle.net/21.15107/rcub_machinery_142 .