Tga-dsc-ms analysis of pyrolysis process of various agricultural residues
Apstrakt
Slow pyrolysis (gradual heating over a wide range of temperatures) characteristics of various biomasses (corn brakes, wheat straw, and hazelnut shell) were investigated by simultaneous thermal analysis (STA-TGA-DTG-DSC), coupled with mass spectrometry. Thermal decomposition of these samples was divided into three stages corresponding to removal of water, devolatilization, and formation of bio-char. It was found that differences in thermal behavior of the samples are due to differences in their composition. The mass spectrometry results showed that H-2, CH4, H2O, CO2 (C3H8), CO, and C2H6 were main gaseous products released during pyrolysis. Within the pyrolysis processes, it was found that CO2 can be used on the large scale for production of CO-rich syngas.
Ključne reči:
volatilization / syngas production / efficient bio-char yields / biomassIzvor:
Thermal Science, 2019, 23, S1457-S1472Izdavač:
- Univerzitet u Beogradu - Institut za nuklearne nauke Vinča, Beograd
Finansiranje / projekti:
- Dinamika nelinearnih fizičkohemijskih i biohemijskih sistema sa modeliranjem i predviđanjem njihovih ponašanja pod neravnotežnim uslovima (RS-MESTD-Basic Research (BR or ON)-172015)
- Smanjenje aerozagađenja iz termoelektrana u JP Elektroprivreda Srbije (RS-MESTD-Integrated and Interdisciplinary Research (IIR or III)-42010)
DOI: 10.2298/TSCI180118182M
ISSN: 0354-9836
WoS: 000509489400006
Scopus: 2-s2.0-85057071584
Kolekcije
Institucija/grupa
Mašinski fakultetTY - JOUR AU - Manić, Nebojša AU - Janković, Bojan AU - Stojiljković, Dragoslava AU - Jovanović, Vladimir AU - Radojević, Miloš PY - 2019 UR - https://machinery.mas.bg.ac.rs/handle/123456789/3151 AB - Slow pyrolysis (gradual heating over a wide range of temperatures) characteristics of various biomasses (corn brakes, wheat straw, and hazelnut shell) were investigated by simultaneous thermal analysis (STA-TGA-DTG-DSC), coupled with mass spectrometry. Thermal decomposition of these samples was divided into three stages corresponding to removal of water, devolatilization, and formation of bio-char. It was found that differences in thermal behavior of the samples are due to differences in their composition. The mass spectrometry results showed that H-2, CH4, H2O, CO2 (C3H8), CO, and C2H6 were main gaseous products released during pyrolysis. Within the pyrolysis processes, it was found that CO2 can be used on the large scale for production of CO-rich syngas. PB - Univerzitet u Beogradu - Institut za nuklearne nauke Vinča, Beograd T2 - Thermal Science T1 - Tga-dsc-ms analysis of pyrolysis process of various agricultural residues EP - S1472 SP - S1457 VL - 23 DO - 10.2298/TSCI180118182M ER -
@article{ author = "Manić, Nebojša and Janković, Bojan and Stojiljković, Dragoslava and Jovanović, Vladimir and Radojević, Miloš", year = "2019", abstract = "Slow pyrolysis (gradual heating over a wide range of temperatures) characteristics of various biomasses (corn brakes, wheat straw, and hazelnut shell) were investigated by simultaneous thermal analysis (STA-TGA-DTG-DSC), coupled with mass spectrometry. Thermal decomposition of these samples was divided into three stages corresponding to removal of water, devolatilization, and formation of bio-char. It was found that differences in thermal behavior of the samples are due to differences in their composition. The mass spectrometry results showed that H-2, CH4, H2O, CO2 (C3H8), CO, and C2H6 were main gaseous products released during pyrolysis. Within the pyrolysis processes, it was found that CO2 can be used on the large scale for production of CO-rich syngas.", publisher = "Univerzitet u Beogradu - Institut za nuklearne nauke Vinča, Beograd", journal = "Thermal Science", title = "Tga-dsc-ms analysis of pyrolysis process of various agricultural residues", pages = "S1472-S1457", volume = "23", doi = "10.2298/TSCI180118182M" }
Manić, N., Janković, B., Stojiljković, D., Jovanović, V.,& Radojević, M.. (2019). Tga-dsc-ms analysis of pyrolysis process of various agricultural residues. in Thermal Science Univerzitet u Beogradu - Institut za nuklearne nauke Vinča, Beograd., 23, S1457-S1472. https://doi.org/10.2298/TSCI180118182M
Manić N, Janković B, Stojiljković D, Jovanović V, Radojević M. Tga-dsc-ms analysis of pyrolysis process of various agricultural residues. in Thermal Science. 2019;23:S1457-S1472. doi:10.2298/TSCI180118182M .
Manić, Nebojša, Janković, Bojan, Stojiljković, Dragoslava, Jovanović, Vladimir, Radojević, Miloš, "Tga-dsc-ms analysis of pyrolysis process of various agricultural residues" in Thermal Science, 23 (2019):S1457-S1472, https://doi.org/10.2298/TSCI180118182M . .